The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Aromatic compounds / Aromatic radicals / C6H5O2 / Caralp(1999)_298K_245-300nm

DATAFILE: C6H5O2_Caralp(1999)_298K_245-300nm.txt
NAME: phenylperoxy radical
FORMULA: C6H5O2
AUTHOR(YEAR): Caralp(1999)
T: 298K
λ: 245-300nm
BIBLIOGRAPHY: F. Caralp, V. Focher, R. Lesclaux, T.J. Wallington, and M.D. Hurley, "Atmospheric chemistry of benzaldehyde: UV absorption spectrum and reaction kinetics and mechanisms of the C6H5C(O)O2 radical", Phys. Chem. Chem. Phys. 1, 3509-3517 (1999); DOI: 10.1039/A903088C
COMMENTS: Flash photolysis/transient UV absorption technique

Photolysis of C6H5CHO/Cl2/O2/N2 mixtures

Values estimated from simulations of decay traces

Absorption cross sections as listed in Table 2

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